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Position the top oven rack in the center position and pre-heat oven to 425°F.
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Place the potatoes in the pre-heated oven and bake until cooked through, approximately 50 minutes. Remove potatoes from oven and transfer to a baking rack to cool for 10 minutes or until cool enough to handle.
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While the potatoes are cooling, combine the tomato sauce, Italian seasoning, and garlic powder in a medium bowl. Season with salt and black pepper, to taste, and stir to combine. Set aside.
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Once cool, cut the potatoes in half lengthwise and carefully scoop out the soft interior with a spoon, leaving a one-quarter inch margin around the skins. (Save the cooked potato filling for another recipe).
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Place the potato skins cut side down on a baking rack set over a baking sheet. Brush the skins with olive oil and return to the hot oven for 10 minutes.
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Remove the baking sheet from the oven and flip over the skins with tongs. Divide the seasoned tomato sauce evenly between the skins and spread into a thin layer with the back of a spoon.
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Fill each skin with an equal amount of Mozzarella cheese, pepperoni, and fresh basil. Place back in the oven for another 10 minutes or until the cheese is melted.
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Remove from oven and cool for a few minutes before serving. Enjoy!